Hi,
Is there anyway to use SSO for Desktop and LDAP for Appian Mobile Apps?
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Yes, both are possible in Appian
To set up SSO through SAML for desktop you can refer to this article: https://docs.appian.com/suite/help/19.2/SAML_for_Single_Sign-On.html
For using LDAP for your Appian mobile app check out this article: https://docs.appian.com/suite/help/19.2/Appian_for_Mobile_Devices.html#client-authentication-requirements