In new 24.4 we have Synchronous and Asynchronous option for Start Process smart service . Then what's the difference between Subprocess Synchronous and Asynchronous things ?
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AFAIK this is basically just a case of "feature convergence" - originally-separate features being fleshed-out (separately) to the point where they become nearly interchangeable, if not totally interchangeable.
They may be planning to phase out the classic subprocess node altogether - though it's impossible to say either way. The "start process" node needs a few more improvements before that can happen, though.