I'm just trying to learn if there is any way that we can introduce business exceptions and system exceptions into the automation flow like the other RPA tools (like try catch ) kind of elements?
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Business and system exceptions should be handled within process model flows. For example, your process model should execute a robotic process and the node will wait for the process to complete. Using the data -> outputs, you can use variables and fields to handle exceptions via process model gateways.
In terms of 'try / catch" style behavior, the conditional actions act as natural flows to help. For example, you can use 'Does window title exist' as a check for a title and then you can have exception logic within the 'No' block.